The Skin of the Vipermagi is a set of unique armor in Diablo 2: Resurrected, which drops randomly, so there’s nowhere in the game that you’re guaranteed to find it. But there are some places where the probability of Skin of the Vipermagi is higher than it is at others. But it’s never very high, so be prepared to grind the same sections of the game a lot if you want to find it. Unless, of course, you get really lucky.
The earliest possible area in which a Skin of the Vipermagi might drop is in
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